常温下,向10mL 0.1mol?L-1的H2C2O4溶液中逐滴加入0.1mol?L-1KOH溶液,所得滴定曲线如图所示.下列说法正

2025-04-08 01:10:12
推荐回答(1个)
回答1:

A.B点时等物质的量的H2C2O4和KOH恰好反应生成KHC2O4,溶液的pH小于7,说明KHC2O4溶液呈弱酸性,故A错误;
B.B点溶液呈酸性,则c(H+)>c(OH-),溶液中存在电荷守恒:c(K+)+c(H+)=c(HC2O4-)+c(OH-)+2c(C2O4 2- ),所以c(K+)>c(HC2O4-),故B正确;
C.C点时,溶液呈中性,c(H+)=c(OH-),结合电荷守恒得c(K+)=c(HC2O4-)+2 c(C2O4 2- ),此点溶液中的溶质是草酸钠,草酸氢根离子水解较微弱,所以所以c(C2O4 2- )>c(H2C2O4),则c(HC2O4-)+2c(C2O4 2- )+c(H2C2O4)<c(K+)<c(HC2O4-)+2 c(C2O4 2- )+c(H2C2O4),故C正确;
D.D点时,氢氧化钾的物质的量是草酸的2倍,二者恰好反应生成草酸钠,根据质子守恒得c(H+)+c(C2O4 2- )+2c(H2C2O4)=c(OH-),故D错误;
故选BC.

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